Actually now having both in my hands. The iPhone actually supports JiveTalk as an actual APP. It's amazing on the iphone, as well as any other app in the app store. There is so much to choose from and it's right at your fingertips.
However, I give an additional point for Jivetalk on the Blackberry, because it can notify (the little number on the icon) me of incoming messages.
Other than that, it's pretty tough. Especially asking here.
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